5,6-Dimethyl-1,10-phenanthroline
نویسندگان
چکیده
منابع مشابه
Aqua(2,9-dimethyl-1,10-phenanthroline-κ2 N,N′)bis(2-hydroxybenzoato-κO)manganese(II) 2,9-dimethyl-1,10-phenanthroline hemisolvate
In the asymmetric unit of the title complex, [Mn(C(7)H(5)O(3))(2)(C(14)H(12)N(2))(H(2)O)]·0.5C(14)H(12)N(2), the Mn(II) ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) mol-ecule, one water mol-ecule and two monodentate 2-hydroxy-benzoate anions in a distorted trigonal-bipyramidal geometry. The OH group of the 2-hydroxy-benzoate anion is disordered over two positions ...
متن کاملDibromido(2,9-dimethyl-1,10-phenanthroline-κ2 N,N′)cadmium
In the title complex, [CdBr(2)(C(14)H(12)N(2))], the Cd(II) ion is tetra-coordinated by two N atoms of the bidentate 2,9-dimethyl-1,10-phenanthroline ligand and two bromide ions in a substanti-ally distorted CdN(2)Br(2) tetra-hedral geometry. In the crystal, inversion dimers linked by pairs of weak C-H⋯Br bonds generate R(2) (2)(14) loops. Aromatic π-π stacking [shortest centroid-centroid separ...
متن کامل(2,9-Dimethyl-1,10-phenanthroline-κ2 N,N′)diiodidocadmium
In the title compound, [CdI(2)(C(14)H(12)N(2))], the mol-ecule sits on a crystallographic twofold axis. The coordination sphere of the Cd(II) atom is built of two symmetry-equivalent N atoms of one 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and two symmetry-equivalent I atoms, thus forming a distorted tetra-hedral geometry. Inversion-related mol-ecules inter-act along the c-axis direction...
متن کاملDichlorido(2,9-dimethyl-1,10-phenanthroline-κ2 N,N′)copper(II)
In the title compound, [CuCl(2)(C(14)H(12)N(2))], the complex molecule has m symmetry, with the mirror plane oriented parallel to the planar molecule and the ligated Cu(II) atom. The metal centre has a distorted tetra-hedral coordination formed by two N atoms from one 2,9-dimethyl-1,10-phenanthroline ligand and two Cl atoms. There is inter-molecular π-π stacking between adjacent 2,9-dimethyl-1,...
متن کاملDibromido(2,9-dimethyl-1,10-phenanthroline-κ2 N,N′)zinc
The reaction of equimolar amounts of zinc bromide and 2,9-dimethyl-1,10-phenanthroline in dry methanol provided the title compound, [ZnBr(2)(C(14)H(12)N(2))], in good yield. The Zn(II) ion is coordinated in a distorted tetra-hedral environment by two N atoms from the chelating 2,9-dimethyl-1,10-phenanthroline ligand and two bromide ions. There is inter-molecular π-π stacking between adjacent ph...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2013
ISSN: 1600-5368
DOI: 10.1107/s1600536813025087